Frustrated Lewis Pairs Database

FLPID: 0AN13011

FLP

LA-LB distance (d/Å): 3.435

hydride affinity (ΔG°H/eV):-3.38

proton affinity (ΔG°H+/eV):8.03

HOMO-LUMO Gap (ΔEg/eV): 5.69

hardness of LA (η/eV):0.105

softness of LA (S/eV):4.780

CM5 charge of LA (e): 0.28

CM5 charge of LB (e): -0.34

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.215

Electronic energy of H2 binding, ΔE = 3.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.247

Electronic energy of H2 binding, ΔE = -16.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.680

Electronic energy of H2 binding, ΔE = -19.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.434

Electronic energy of H2 binding, ΔE = -22.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.470

Electronic energy of H2 binding, ΔE = -18.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.696

Electronic energy of H2 binding, ΔE = -20.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.1 kcal/mol

xyz coordinates: Download