Frustrated Lewis Pairs Database

FLPID: 0BP17031

FLP

LA-LB distance (d/Å):2.999

hydride affinity (ΔG°H/eV) :-4.75

proton affinity (ΔG°H+/eV) :8.35

HOMO-LUMO Gap (ΔEg/eV):5.4

hardness of LA (η/eV):0.100

softness of LA (S/eV):5.015

CM5 charge of LA (e):-0.077

CM5 charge of LB (e):0.012

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):2.736

Electronic energy of H2 binding, ΔE = -2.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):2.755

Electronic energy of H2 binding, ΔE = -7.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.033

Electronic energy of H2 binding, ΔE = -15.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.029

Electronic energy of H2 binding, ΔE = -9.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.019

Electronic energy of H2 binding, ΔE = -11.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.042

Electronic energy of H2 binding, ΔE = -16.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.6 kcal/mol

xyz coordinates: Download