Frustrated Lewis Pairs Database

FLPID: 0AP16011

FLP

LA-LB distance (d/Å):3.263

hydride affinity (ΔG°H/eV) :-3.71

proton affinity (ΔG°H+/eV) :7.90

HOMO-LUMO Gap (ΔEg/eV):7.0

hardness of LA (η/eV):0.129

softness of LA (S/eV):3.884

CM5 charge of LA (e):0.305

CM5 charge of LB (e):-0.004

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.253

Electronic energy of H2 binding, ΔE = 15.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 18.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 4.790

Electronic energy of H2 binding, ΔE = -45.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -43.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -31.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.321

Electronic energy of H2 binding, ΔE = -21.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.332

Electronic energy of H2 binding, ΔE = -16.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.103

Electronic energy of H2 binding, ΔE = -27.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.329

Electronic energy of H2 binding, ΔE = -19.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.5 kcal/mol

xyz coordinates: Download