Frustrated Lewis Pairs Database

FLPID: 0AP19012

FLP

LA-LB distance (d/Å):3.133

hydride affinity (ΔG°H/eV) :-3.64

proton affinity (ΔG°H+/eV) :7.32

HOMO-LUMO Gap (ΔEg/eV):6.3

hardness of LA (η/eV):0.115

softness of LA (S/eV):4.330

CM5 charge of LA (e):0.272

CM5 charge of LB (e):-0.007

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.065

Electronic energy of H2 binding, ΔE = 3.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.176

Electronic energy of H2 binding, ΔE = -4.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.329

Electronic energy of H2 binding, ΔE = -23.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.209

Electronic energy of H2 binding, ΔE = -11.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.157

Electronic energy of H2 binding, ΔE = -42.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -42.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -30.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.259

Electronic energy of H2 binding, ΔE = -23.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.1 kcal/mol

xyz coordinates: Download