Frustrated Lewis Pairs Database

FLPID: 0AP19011

FLP

LA-LB distance (d/Å):3.275

hydride affinity (ΔG°H/eV) :-3.67

proton affinity (ΔG°H+/eV) :7.39

HOMO-LUMO Gap (ΔEg/eV):6.1

hardness of LA (η/eV):0.111

softness of LA (S/eV):4.486

CM5 charge of LA (e):0.260

CM5 charge of LB (e):-0.010

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.135

Electronic energy of H2 binding, ΔE = 4.8kcal/mol

Ethalpy of H2 binding, ΔH° = 8.0kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.8kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.092

Electronic energy of H2 binding, ΔE = -21.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.3 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.265

Electronic energy of H2 binding, ΔE = -18.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.265

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.277

Electronic energy of H2 binding, ΔE = -27.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 26.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.2kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.289

Electronic energy of H2 binding, ΔE = -19.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.8kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.8 kcal/mol

xyz coordinates: Download