Frustrated Lewis Pairs Database

FLPID: 0BP16042

FLP

LA-LB distance (d/Å):2.237

hydride affinity (ΔG°H/eV) :-4.79

proton affinity (ΔG°H+/eV) :7.66

HOMO-LUMO Gap (ΔEg/eV): 6.8

hardness of LA (η/eV):0.125

softness of LA (S/eV):4.005

CM5 charge of LA (e): -0.176

CM5 charge of LB (e): -0.121

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.111

Electronic energy of H2 binding, ΔE = -13.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.096

Electronic energy of H2 binding, ΔE = -13.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.198

Electronic energy of H2 binding, ΔE = -18.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.868

Electronic energy of H2 binding, ΔE = -38.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.277

Electronic energy of H2 binding, ΔE = -30.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -17.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.193

Electronic energy of H2 binding, ΔE = -20.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.4 kcal/mol

xyz coordinates: Download