Frustrated Lewis Pairs Database

FLPID: 0BP16041

FLP

LA-LB distance (d/Å):2.235

hydride affinity (ΔG°H/eV) :-4.75

proton affinity (ΔG°H+/eV) :7.63

HOMO-LUMO Gap (ΔEg/eV):6.9

hardness of LA (η/eV):0.128

softness of LA (S/eV):3.918

CM5 charge of LA (e):-0.177

CM5 charge of LB (e):0.120

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.105

Electronic energy of H2 binding, ΔE = -13.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.096

Electronic energy of H2 binding, ΔE = -13.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.244

Electronic energy of H2 binding, ΔE = -23.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.107

Electronic energy of H2 binding, ΔE = -37.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.395

Electronic energy of H2 binding, ΔE = -24.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.239

Electronic energy of H2 binding, ΔE = -24.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.8 kcal/mol

xyz coordinates: Download