Frustrated Lewis Pairs Database

FLPID: 0BP19052

FLP

LA-LB distance (d/Å): 2.174

hydride affinity (ΔG°H/eV) :-4.50

proton affinity (ΔG°H+/eV) :7.87

HOMO-LUMO Gap (ΔEg/eV): 6.8

hardness of LA (η/eV):0.125

softness of LA (S/eV):4.002

CM5 charge of LA (e): -0.186

CM5 charge of LB (e): 0.125

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.117

Electronic energy of H2 binding, ΔE = -6.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.100

Electronic energy of H2 binding, ΔE = -8.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.211

Electronic energy of H2 binding, ΔE = -19.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.106

Electronic energy of H2 binding, ΔE = -35.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -17.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.212

Electronic energy of H2 binding, ΔE = -24.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.180

Electronic energy of H2 binding, ΔE = -17.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.9 kcal/mol

xyz coordinates: Download