Frustrated Lewis Pairs Database

FLPID: 0BP19051

FLP

LA-LB distance (d/Å): 2.238

hydride affinity (ΔG°H/eV) :-4.63

proton affinity (ΔG°H+/eV) :7.42

HOMO-LUMO Gap (ΔEg/eV): 6.3

hardness of LA (η/eV):0.116

softness of LA (S/eV):4.307

CM5 charge of LA (e): -0.180

CM5 charge of LB (e): 0.122

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.182

Electronic energy of H2 binding, ΔE = -11.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.126

Electronic energy of H2 binding, ΔE = -11.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.233

Electronic energy of H2 binding, ΔE = -19.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.1kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.130

Electronic energy of H2 binding, ΔE = -38.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.510

Electronic energy of H2 binding, ΔE = -12.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.226

Electronic energy of H2 binding, ΔE = -19.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.4 kcal/mol

xyz coordinates: Download