Frustrated Lewis Pairs Database

FLPID: 0BP19041

FLP

LA-LB distance (d/Å):4.434

hydride affinity (ΔG°H/eV) :-4.85

proton affinity (ΔG°H+/eV) :7.94

HOMO-LUMO Gap (ΔEg/eV):5.2

hardness of LA (η/eV):0.096

softness of LA (S/eV):5.198

CM5 charge of LA (e):-0.070

CM5 charge of LB (e):-0.004

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = 0.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):4.062

Electronic energy of H2 binding, ΔE = 2.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 2.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):4.394

Electronic energy of H2 binding, ΔE = -21.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.328

Electronic energy of H2 binding, ΔE = -14.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.555

Electronic energy of H2 binding, ΔE = -15.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.411

Electronic energy of H2 binding, ΔE = -21.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.8 kcal/mol

xyz coordinates: Download