Frustrated Lewis Pairs Database

FLPID: 0BP15023

FLP

LA-LB distance (d/Å): 4.386

hydride affinity (ΔG°H/eV):-4.82

proton affinity (ΔG°H+/eV):7.67

HOMO-LUMO Gap (ΔEg/eV): 5.15

hardness of LA (η/eV):0.095

softness of LA (S/eV):5.289

CM5 charge of LA (e): -0.07

CM5 charge of LB (e): -0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 4.438

Electronic energy of H2 binding, ΔE = -7.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 4.149

Electronic energy of H2 binding, ΔE = -4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 4.158

Electronic energy of H2 binding, ΔE = -22.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.363

Electronic energy of H2 binding, ΔE = -8.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.583

Electronic energy of H2 binding, ΔE = -11.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.169

Electronic energy of H2 binding, ΔE = -22.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.2 kcal/mol

xyz coordinates: Download