Frustrated Lewis Pairs Database

FLPID: 0BP15022

FLP

LA-LB distance (d/Å): 4.084

hydride affinity (ΔG°H/eV):-4.89

proton affinity (ΔG°H+/eV):7.51

HOMO-LUMO Gap (ΔEg/eV): 4.93

hardness of LA (η/eV):0.091

softness of LA (S/eV):5.515

CM5 charge of LA (e): -0.06

CM5 charge of LB (e): -0.00

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 4.029

Electronic energy of H2 binding, ΔE = -9.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.964

Electronic energy of H2 binding, ΔE = 4.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 19.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):4.089

Electronic energy of H2 binding, ΔE = -26.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.883

Electronic energy of H2 binding, ΔE = -26.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.490

Electronic energy of H2 binding, ΔE = -27.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.8kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.263

Electronic energy of H2 binding, ΔE = -23.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.8 kcal/mol

xyz coordinates: Download