Frustrated Lewis Pairs Database

FLPID: 0BP15021

FLP

LA-LB distance (d/Å): 5.433

hydride affinity (ΔG°H/eV):-4.93

proton affinity (ΔG°H+/eV):7.65

HOMO-LUMO Gap (ΔEg/eV): 4.77

hardness of LA (η/eV):0.088

softness of LA (S/eV):5.700

CM5 charge of LA (e): -0.06

CM5 charge of LB (e): -0.01

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 5.169

Electronic energy of H2 binding, ΔE = -4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 5.466

Electronic energy of H2 binding, ΔE = -1.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 5.275

Electronic energy of H2 binding, ΔE = -19.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):5.298

Electronic energy of H2 binding, ΔE = -19.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):5.227

Electronic energy of H2 binding, ΔE = -17.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):5.253

Electronic energy of H2 binding, ΔE = -20.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.9 kcal/mol

xyz coordinates: Download