Frustrated Lewis Pairs Database

FLPID: 0BP15011

FLP

LA-LB distance (d/Å): 5.195

hydride affinity (ΔG°H/eV):-4.97

proton affinity (ΔG°H+/eV):7.57

HOMO-LUMO Gap (ΔEg/eV): 5.23

hardness of LA (η/eV):0.096

softness of LA (S/eV):5.205

CM5 charge of LA (e): -0.07

CM5 charge of LB (e): -0.01

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -8.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 5.218

Electronic energy of H2 binding, ΔE = -8.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.3 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 5.385

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):5.336

Electronic energy of H2 binding, ΔE = -20.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.240

Electronic energy of H2 binding, ΔE = -35.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.084

Electronic energy of H2 binding, ΔE = -21.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.0 kcal/mol

xyz coordinates: Download