Frustrated Lewis Pairs Database

FLPID: 0BP16061

FLP

LA-LB distance (d/Å): 2.938

hydride affinity (ΔG°H/eV):-4.66

proton affinity (ΔG°H+/eV):7.86

HOMO-LUMO Gap (ΔEg/eV): 5.70

hardness of LA (η/eV):0.105

softness of LA (S/eV):4.773

CM5 charge of LA (e): -0.08

CM5 charge of LB (e): -0.02

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.831

Electronic energy of H2 binding, ΔE = -16.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.737

Electronic energy of H2 binding, ΔE = -23.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.915

Electronic energy of H2 binding, ΔE = -13.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.891

Electronic energy of H2 binding, ΔE = -52.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -49.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -35.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):2.944

Electronic energy of H2 binding, ΔE = -35.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):2.950

Electronic energy of H2 binding, ΔE = -18.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.3 kcal/mol

xyz coordinates: Download