Frustrated Lewis Pairs Database

FLPID: 0BP19031

FLP

LA-LB distance (d/Å): 2.955

hydride affinity (ΔG°H/eV):-3.63

proton affinity (ΔG°H+/eV):7.52

HOMO-LUMO Gap (ΔEg/eV): 4.21

hardness of LA (η/eV):0.077

softness of LA (S/eV):6.467

CM5 charge of LA (e): -0.09

CM5 charge of LB (e): -0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.957

Electronic energy of H2 binding, ΔE = -5.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.738

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.900

Electronic energy of H2 binding, ΔE = -8.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.924

Electronic energy of H2 binding, ΔE = -42.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -40.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -25.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.910

Electronic energy of H2 binding, ΔE = -32.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 2.920

Electronic energy of H2 binding, ΔE = -11.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.1 kcal/mol

xyz coordinates: Download