Frustrated Lewis Pairs Database

FLPID: 0ṠP19012

FLP

LA-LB distance (d/Å): 3.435

hydride affinity (ΔG°H/eV):-3.74

proton affinity (ΔG°H+/eV):7.69

HOMO-LUMO Gap (ΔEg/eV): 5.38

hardness of LA (η/eV):0.099

softness of LA (S/eV):5.062

CM5 charge of LA (e): 0.18

CM5 charge of LB (e): -0.04

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = 4.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 8.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 16.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.109

Electronic energy of H2 binding, ΔE = 4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 16.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.438

Electronic energy of H2 binding, ΔE = -3.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.435

Electronic energy of H2 binding, ΔE = -2.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.444

Electronic energy of H2 binding, ΔE = -7.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.537

Electronic energy of H2 binding, ΔE = 4.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.4 kcal/mol

xyz coordinates: Download