Frustrated Lewis Pairs Database

FLPID: 0ṠP19011

FLP

LA-LB distance (d/Å): 3.359

hydride affinity (ΔG°H/eV):-2.57

proton affinity (ΔG°H+/eV):7.92

HOMO-LUMO Gap (ΔEg/eV): 5.84

hardness of LA (η/eV):0.107

softness of LA (S/eV):4.659

CM5 charge of LA (e): 0.44

CM5 charge of LB (e): -0.04

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.357

Electronic energy of H2 binding, ΔE = -0.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.062

Electronic energy of H2 binding, ΔE = -3.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.192

Electronic energy of H2 binding, ΔE = -9.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.363

Electronic energy of H2 binding, ΔE = -3.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.364

Electronic energy of H2 binding, ΔE = -8.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.192

Electronic energy of H2 binding, ΔE = -9.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.2 kcal/mol

xyz coordinates: Download