Frustrated Lewis Pairs Database

FLPID: 0BP20011

FLP

LA-LB distance (d/Å): 1.993

hydride affinity (ΔG°H/eV):-2.86

proton affinity (ΔG°H+/eV):7.55

HOMO-LUMO Gap (ΔEg/eV): 6.99

hardness of LA (η/eV):0.128

softness of LA (S/eV):3.892

CM5 charge of LA (e): 0.05

CM5 charge of LB (e): -0.05

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 4.096

Electronic energy of H2 binding, ΔE = -20.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 4.051

Electronic energy of H2 binding, ΔE = -28.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 1.999

Electronic energy of H2 binding, ΔE = -8.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.017

Electronic energy of H2 binding, ΔE = -2.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.940

Electronic energy of H2 binding, ΔE = -37.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -39.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -32.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 1.994

Electronic energy of H2 binding, ΔE = -2.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.4 kcal/mol

xyz coordinates: Download