Frustrated Lewis Pairs Database

FLPID: 0BP06011

FLP

LA-LB distance (d/Å): 3.149

hydride affinity (ΔG°H/eV):-4.48

proton affinity (ΔG°H+/eV):7.48

HOMO-LUMO Gap (ΔEg/eV): 5.13

hardness of LA (η/eV):0.094

softness of LA (S/eV):5.304

CM5 charge of LA (e): -0.10

CM5 charge of LB (e): 0.01

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.097

Electronic energy of H2 binding, ΔE = -18.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.209

Electronic energy of H2 binding, ΔE = -14.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.347

Electronic energy of H2 binding, ΔE = -18.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.524

Electronic energy of H2 binding, ΔE = -7.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.188

Electronic energy of H2 binding, ΔE = -38.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -36.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.346

Electronic energy of H2 binding, ΔE = -20.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.1 kcal/mol

xyz coordinates: Download