Frustrated Lewis Pairs Database

FLPID: 0BP20051

FLP

LA-LB distance (d/Å): 2.086

hydride affinity (ΔG°H/eV):-4.59

proton affinity (ΔG°H+/eV):7.98

HOMO-LUMO Gap (ΔEg/eV): 7.02

hardness of LA (η/eV):0.129

softness of LA (S/eV):3.874

CM5 charge of LA (e): -0.21

CM5 charge of LB (e): 0.11

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.055

Electronic energy of H2 binding, ΔE = -7.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.127

Electronic energy of H2 binding, ΔE = -7.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.027

Electronic energy of H2 binding, ΔE = -3.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.139

Electronic energy of H2 binding, ΔE = -36.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.407

Electronic energy of H2 binding, ΔE = -27.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.591

Electronic energy of H2 binding, ΔE = -15.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.9 kcal/mol

xyz coordinates: Download