Frustrated Lewis Pairs Database

FLPID: 0BP18011

FLP

LA-LB distance (d/Å): 2.868

hydride affinity (ΔG°H/eV):-4.61

proton affinity (ΔG°H+/eV):7.89

HOMO-LUMO Gap (ΔEg/eV): 5.95

hardness of LA (η/eV):0.109

softness of LA (S/eV):4.570

CM5 charge of LA (e): 0.02

CM5 charge of LB (e): 0.13

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.648

Electronic energy of H2 binding, ΔE = -15.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.533

Electronic energy of H2 binding, ΔE = -10.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.689

Electronic energy of H2 binding, ΔE = -32.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.855

Electronic energy of H2 binding, ΔE = -6.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):2.847

Electronic energy of H2 binding, ΔE = -37.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -37.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -16.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.9 kcal/mol

xyz coordinates: Download