Frustrated Lewis Pairs Database

FLPID: 0BP19021

FLP

LA-LB distance (d/Å): 2.756

hydride affinity (ΔG°H/eV):-4.25

proton affinity (ΔG°H+/eV):7.99

HOMO-LUMO Gap (ΔEg/eV): 4.20

hardness of LA (η/eV):0.123

softness of LA (S/eV):4.078

CM5 charge of LA (e): -0.07

CM5 charge of LB (e): -0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.563

Electronic energy of H2 binding, ΔE = -9.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.426

Electronic energy of H2 binding, ΔE = -11.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.629

Electronic energy of H2 binding, ΔE = -13.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.838

Electronic energy of H2 binding, ΔE = -36.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -33.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):2.710

Electronic energy of H2 binding, ΔE = -37.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -15.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.9 kcal/mol

xyz coordinates: Download