Frustrated Lewis Pairs Database

FLPID: 0BP06011

FLP

LA-LB distance (d/Å): 3.056

hydride affinity (ΔG°H/eV):-3.02

proton affinity (ΔG°H+/eV):7.11

HOMO-LUMO Gap (ΔEg/eV): 7.06

hardness of LA (η/eV):0.130

softness of LA (S/eV):3.853

CM5 charge of LA (e): 0.05

CM5 charge of LB (e): -0.37

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.073

Electronic energy of H2 binding, ΔE = -14.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.876

Electronic energy of H2 binding, ΔE = -24.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.054

Electronic energy of H2 binding, ΔE = -33.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -17.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.084

Electronic energy of H2 binding, ΔE = -40.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -36.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.057

Electronic energy of H2 binding, ΔE = -40.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -38.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -24.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.162

Electronic energy of H2 binding, ΔE = -32.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.7 kcal/mol

xyz coordinates: Download