Frustrated Lewis Pairs Database

FLPID: 0BP09021

FLP

LA-LB distance (d/Å): 1.756

hydride affinity (ΔG°H/eV):-5.02

proton affinity (ΔG°H+/eV):9.43

HOMO-LUMO Gap (ΔEg/eV): 3.97

hardness of LA (η/eV):0.073

softness of LA (S/eV):6.852

CM5 charge of LA (e): -0.20

CM5 charge of LB (e): 0.08

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 1.952

Electronic energy of H2 binding, ΔE = -40.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -36.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -27.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 1.998

Electronic energy of H2 binding, ΔE = -19.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.017

Electronic energy of H2 binding, ΔE = -49.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -49.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -37.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 1.997

Electronic energy of H2 binding, ΔE = -18.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.005

Electronic energy of H2 binding, ΔE = -42.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -44.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -36.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 1.969

Electronic energy of H2 binding, ΔE = -23.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.9 kcal/mol

xyz coordinates: Download