Frustrated Lewis Pairs Database

FLPID: 0BP17021

FLP

LA-LB distance (d/Å): 3.187

hydride affinity (ΔG°H/eV):-5.05

proton affinity (ΔG°H+/eV):7.95

HOMO-LUMO Gap (ΔEg/eV): 4.65

hardness of LA (η/eV):0.085

softness of LA (S/eV):5.853

CM5 charge of LA (e): 0.00

CM5 charge of LB (e): -0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.206

Electronic energy of H2 binding, ΔE = -8.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.279

Electronic energy of H2 binding, ΔE = -21.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.354

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.190

Electronic energy of H2 binding, ΔE = -38.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.082

Electronic energy of H2 binding, ΔE = -30.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.500

Electronic energy of H2 binding, ΔE = -16.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.6 kcal/mol

xyz coordinates: Download