Frustrated Lewis Pairs Database

FLPID: 0BP19011

FLP

LA-LB distance (d/Å): 3.394

hydride affinity (ΔG°H/eV):-4.12

proton affinity (ΔG°H+/eV):7.55

HOMO-LUMO Gap (ΔEg/eV): 5.60

hardness of LA (η/eV):0.103

softness of LA (S/eV):4.856

CM5 charge of LA (e): -0.16

CM5 charge of LB (e): 0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.402

Electronic energy of H2 binding, ΔE = -6.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.971

Electronic energy of H2 binding, ΔE = -6.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.379

Electronic energy of H2 binding, ΔE = -15.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.028

Electronic energy of H2 binding, ΔE = -38.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.034

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.356

Electronic energy of H2 binding, ΔE = -22.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.5 kcal/mol

xyz coordinates: Download