Frustrated Lewis Pairs Database

FLPID: 0BP16051

FLP

LA-LB distance (d/Å): 2.082

hydride affinity (ΔG°H/eV):-5.04

proton affinity (ΔG°H+/eV):

HOMO-LUMO Gap (ΔEg/eV): 6.47

hardness of LA (η/eV):0.119

softness of LA (S/eV):4.208

CM5 charge of LA (e): -0.22

CM5 charge of LB (e): 0.16

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.960

Electronic energy of H2 binding, ΔE = -6.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.168

Electronic energy of H2 binding, ΔE = 0.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.347

Electronic energy of H2 binding, ΔE = -14.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.174

Electronic energy of H2 binding, ΔE = -38.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.347

Electronic energy of H2 binding, ΔE = -14.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -14.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.7 kcal/mol

xyz coordinates: Download