Frustrated Lewis Pairs Database

FLPID: 0BP08012

FLP

LA-LB distance (d/Å): 1.790

hydride affinity (ΔG°H/eV):-4.74

proton affinity (ΔG°H+/eV):8.23

HOMO-LUMO Gap (ΔEg/eV): 6.69

hardness of LA (η/eV):0.123

softness of LA (S/eV):4.067

CM5 charge of LA (e): -0.16

CM5 charge of LB (e): 0.06

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 1.989

Electronic energy of H2 binding, ΔE = -35.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.105

Electronic energy of H2 binding, ΔE = -14.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.209

Electronic energy of H2 binding, ΔE = -41.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -41.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -27.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 1.993

Electronic energy of H2 binding, ΔE = -4.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.119

Electronic energy of H2 binding, ΔE = -42.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -41.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -25.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 2.031

Electronic energy of H2 binding, ΔE = -12.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.2 kcal/mol

xyz coordinates: Download