Frustrated Lewis Pairs Database

FLPID: 0BP17011

FLP

LA-LB distance (d/Å): 3.846

hydride affinity (ΔG°H/eV):-5.00

proton affinity (ΔG°H+/eV):7.52

HOMO-LUMO Gap (ΔEg/eV): 4.90

hardness of LA (η/eV):0.090

softness of LA (S/eV):5.557

CM5 charge of LA (e): -0.05

CM5 charge of LB (e): -0.01

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.612

Electronic energy of H2 binding, ΔE = -16.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.388

Electronic energy of H2 binding, ΔE = -0.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 0.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.3 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.557

Electronic energy of H2 binding, ΔE = -8.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.096

Electronic energy of H2 binding, ΔE = -3.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.938

Electronic energy of H2 binding, ΔE = -16.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.586

Electronic energy of H2 binding, ΔE = -12.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.0 kcal/mol

xyz coordinates: Download