Frustrated Lewis Pairs Database

FLPID: 0BP13022

FLP

LA-LB distance (d/Å): 2.019

hydride affinity (ΔG°H/eV):-4.10

proton affinity (ΔG°H+/eV):8.59

HOMO-LUMO Gap (ΔEg/eV): 6.90

hardness of LA (η/eV):0.127

softness of LA (S/eV):3.942

CM5 charge of LA (e): -0.23

CM5 charge of LB (e): 0.14

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.033

Electronic energy of H2 binding, ΔE = 1.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.036

Electronic energy of H2 binding, ΔE = -3.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.260

Electronic energy of H2 binding, ΔE = -6.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.078

Electronic energy of H2 binding, ΔE = -32.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.049

Electronic energy of H2 binding, ΔE = -17.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.193

Electronic energy of H2 binding, ΔE = -9.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.1 kcal/mol

xyz coordinates: Download