Frustrated Lewis Pairs Database

FLPID: 0BP13021

FLP

LA-LB distance (d/Å): 2.028

hydride affinity (ΔG°H/eV):-4.68

proton affinity (ΔG°H+/eV):8.72

HOMO-LUMO Gap (ΔEg/eV): 6.55

hardness of LA (η/eV):0.120

softness of LA (S/eV):4.157

CM5 charge of LA (e): -0.22

CM5 charge of LB (e): 0.15

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.233

Electronic energy of H2 binding, ΔE = -0.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.078

Electronic energy of H2 binding, ΔE = 0.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.211

Electronic energy of H2 binding, ΔE = -8.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.060

Electronic energy of H2 binding, ΔE = -4.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.029

Electronic energy of H2 binding, ΔE = -10.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.408

Electronic energy of H2 binding, ΔE = -8.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download