Frustrated Lewis Pairs Database

FLPID: 0BP14011

FLP

LA-LB distance (d/Å): 3.253

hydride affinity (ΔG°H/eV):-3.24

proton affinity (ΔG°H+/eV):7.81

HOMO-LUMO Gap (ΔEg/eV): 5.55

hardness of LA (η/eV):0.102

softness of LA (S/eV):4.903

CM5 charge of LA (e): 0.06

CM5 charge of LB (e): -0.01

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.295

Electronic energy of H2 binding, ΔE = 18.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 21.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 32.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.016

Electronic energy of H2 binding, ΔE = 4.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.211

Electronic energy of H2 binding, ΔE = -8.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.239

Electronic energy of H2 binding, ΔE = -24.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.232

Electronic energy of H2 binding, ΔE = -12.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.0 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.247

Electronic energy of H2 binding, ΔE = -9.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.5 kcal/mol

xyz coordinates: Download