Frustrated Lewis Pairs Database

FLPID: 0BN15021

FLP

LA-LB distance (d/Å):3.344

hydride affinity (ΔG°H/eV) :-4.86

proton affinity (ΔG°H+/eV) :7.81

HOMO-LUMO Gap (ΔEg/eV):4.9

hardness of LA (η/eV):0.090

softness of LA (S/eV):5.577

CM5 charge of LA (e):-0.064

CM5 charge of LB (e):-0.340

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.257

Electronic energy of H2 binding, ΔE = -13.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.405

Electronic energy of H2 binding, ΔE = 12.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 28.3 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.476

Electronic energy of H2 binding, ΔE = -27.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -27.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -11.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.472

Electronic energy of H2 binding, ΔE = -28.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.5 kcal/mol

xyz coordinates: Download