Frustrated Lewis Pairs Database

FLPID: 0BP08011

FLP

LA-LB distance (d/Å): 1.807

hydride affinity (ΔG°H/eV):-4.78

proton affinity (ΔG°H+/eV):8.45

HOMO-LUMO Gap (ΔEg/eV): 6.66

hardness of LA (η/eV):0.122

softness of LA (S/eV):4.083

CM5 charge of LA (e): -0.14

CM5 charge of LB (e): 0.03

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 1.949

Electronic energy of H2 binding, ΔE = -34.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.043

Electronic energy of H2 binding, ΔE = -12.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 2.078

Electronic energy of H2 binding, ΔE = -38.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -38.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -24.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):1.814

Electronic energy of H2 binding, ΔE = -3.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.127

Electronic energy of H2 binding, ΔE = -39.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -38.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 2.137

Electronic energy of H2 binding, ΔE = -7.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.3 kcal/mol

xyz coordinates: Download