Frustrated Lewis Pairs Database

FLPID: 0BN14016

FLP

LA-LB distance (d/Å):3.462

hydride affinity (ΔG°H/eV) :-5.09

proton affinity (ΔG°H+/eV) :7.92

HOMO-LUMO Gap (ΔEg/eV):4.6

hardness of LA (η/eV):0.085

softness of LA (S/eV):5.856

CM5 charge of LA (e):-0.056

CM5 charge of LB (e):-0.317

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.178

Electronic energy of H2 binding, ΔE = -14.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = 2.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -31.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -17.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -33.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -14.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -36.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -33.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -32.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -31.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.0 kcal/mol

xyz coordinates: Download