Frustrated Lewis Pairs Database

FLPID: 0BN14015

FLP

LA-LB distance (d/Å):3.778

hydride affinity (ΔG°H/eV) :-5.12

proton affinity (ΔG°H+/eV) :7.73

HOMO-LUMO Gap (ΔEg/eV):5.5

hardness of LA (η/eV):0.101

softness of LA (S/eV):4.970

CM5 charge of LA (e):-0.059

CM5 charge of LB (e):-0.333

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.317

Electronic energy of H2 binding, ΔE = -20.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.361

Electronic energy of H2 binding, ΔE = -0.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 16.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.476

Electronic energy of H2 binding, ΔE = -37.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -24.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -46.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -43.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -28.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.510

Electronic energy of H2 binding, ΔE = -36.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.0 kcal/mol

xyz coordinates: Download