Frustrated Lewis Pairs Database

FLPID: 0BN14014

FLP

LA-LB distance (d/Å):3.119

hydride affinity (ΔG°H/eV) :-5.03

proton affinity (ΔG°H+/eV) :7.88

HOMO-LUMO Gap (ΔEg/eV):5.4

hardness of LA (η/eV):0.099

softness of LA (S/eV):5.068

CM5 charge of LA (e):-0.057

CM5 charge of LB (e):-0.321

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.138

Electronic energy of H2 binding, ΔE = -16.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.264

Electronic energy of H2 binding, ΔE = -1.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.308

Electronic energy of H2 binding, ΔE = -34.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -32.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -39.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -37.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.346

Electronic energy of H2 binding, ΔE = -35.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -33.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -17.9 kcal/mol

xyz coordinates: Download