Frustrated Lewis Pairs Database

FLPID: 0BN14013

FLP

LA-LB distance (d/Å):3.250

hydride affinity (ΔG°H/eV) :-4.95

proton affinity (ΔG°H+/eV) :7.57

HOMO-LUMO Gap (ΔEg/eV):5.7

hardness of LA (η/eV):0.105

softness of LA (S/eV):4.743

CM5 charge of LA (e):-0.050

CM5 charge of LB (e):-0.327

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.242

Electronic energy of H2 binding, ΔE = -23.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.403

Electronic energy of H2 binding, ΔE = -7.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.369

Electronic energy of H2 binding, ΔE = -41.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -38.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -25.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -35.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -31.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -48.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -45.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -32.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.395

Electronic energy of H2 binding, ΔE = -39.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -37.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -24.4 kcal/mol

xyz coordinates: Download