Frustrated Lewis Pairs Database

FLPID: 0BN14012

FLP

LA-LB distance (d/Å):3.247

hydride affinity (ΔG°H/eV) :-5.06

proton affinity (ΔG°H+/eV) :7.76

HOMO-LUMO Gap (ΔEg/eV):5.8

hardness of LA (η/eV):0.107

softness of LA (S/eV):4.678

CM5 charge of LA (e):-0.051

CM5 charge of LB (e):-0.329

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.221

Electronic energy of H2 binding, ΔE = -20.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.401

Electronic energy of H2 binding, ΔE = -4.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.357

Electronic energy of H2 binding, ΔE = -39.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -36.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -24.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.371

Electronic energy of H2 binding, ΔE = -33.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -14.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.547

Electronic energy of H2 binding, ΔE = -46.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -43.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -30.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.398

Electronic energy of H2 binding, ΔE = -37.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.1 kcal/mol

xyz coordinates: Download