Frustrated Lewis Pairs Database

FLPID: 0BN14011

FLP

LA-LB distance (d/Å):3.508

hydride affinity (ΔG°H/eV) :-4.95

proton affinity (ΔG°H+/eV) :7.75

HOMO-LUMO Gap (ΔEg/eV):5.3

hardness of LA (η/eV):0.097

softness of LA (S/eV):5.140

CM5 charge of LA (e):-0.063

CM5 charge of LB (e):-0.330

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.257

Electronic energy of H2 binding, ΔE = -18.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.386

Electronic energy of H2 binding, ΔE = -5.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.392

Electronic energy of H2 binding, ΔE = -37.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.347

Electronic energy of H2 binding, ΔE = -34.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.658

Electronic energy of H2 binding, ΔE = -43.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -40.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -27.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.493

Electronic energy of H2 binding, ΔE = -37.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.7 kcal/mol

xyz coordinates: Download