Frustrated Lewis Pairs Database

FLPID: 0BN11031

FLP

LA-LB distance (d/Å):3.258

hydride affinity (ΔG°H/eV) :-5.08

proton affinity (ΔG°H+/eV) :7.85

HOMO-LUMO Gap (ΔEg/eV):5.3

hardness of LA (η/eV):0.098

softness of LA (S/eV):5.127

CM5 charge of LA (e):-0.058

CM5 charge of LB (e):-0.329

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.189

Electronic energy of H2 binding, ΔE = -15.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.350

Electronic energy of H2 binding, ΔE = -1.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 0.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.344

Electronic energy of H2 binding, ΔE = -32.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -1.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 0.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.531

Electronic energy of H2 binding, ΔE = -37.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -35.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -34.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.6 kcal/mol

xyz coordinates: Download