Frustrated Lewis Pairs Database

FLPID: 0BP16023

FLP

LA-LB distance (d/Å):2.095

hydride affinity (ΔG°H/eV) :-4.46

proton affinity (ΔG°H+/eV) :7.86

HOMO-LUMO Gap (ΔEg/eV):7.7

hardness of LA (η/eV):0.142

softness of LA (S/eV):3.532

CM5 charge of LA (e):-0.215

CM5 charge of LB (e):0.157

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.584

Electronic energy of H2 binding, ΔE = 0.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.676

Electronic energy of H2 binding, ΔE = 11.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 12.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 20.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.676

Electronic energy of H2 binding, ΔE = -14.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -22.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.187

Electronic energy of H2 binding, ΔE = -9.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 8.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.077

Electronic energy of H2 binding, ΔE = -12.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.1 kcal/mol

xyz coordinates: Download