Frustrated Lewis Pairs Database

FLPID: 0BP16022

FLP

LA-LB distance (d/Å):2.142

hydride affinity (ΔG°H/eV) :-4.48

proton affinity (ΔG°H+/eV) :7.87

HOMO-LUMO Gap (ΔEg/eV):7.8

hardness of LA (η/eV):0.143

softness of LA (S/eV):3.509

CM5 charge of LA (e):-0.204

CM5 charge of LB (e):0.150

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.593

Electronic energy of H2 binding, ΔE = 0.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.528

Electronic energy of H2 binding, ΔE = 10.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 22.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.672

Electronic energy of H2 binding, ΔE = -15.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = 5.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -23.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -8.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.8 kcal/mol

xyz coordinates: Download