Frustrated Lewis Pairs Database

FLPID: 0BP09014

FLP

LA-LB distance (d/Å):2.149

hydride affinity (ΔG°H/eV) :-4.57

proton affinity (ΔG°H+/eV) :7.67

HOMO-LUMO Gap (ΔEg/eV):7.4

hardness of LA (η/eV):0.136

softness of LA (S/eV):3.671

CM5 charge of LA (e):-0.185

CM5 charge of LB (e):0.122

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.413

Electronic energy of H2 binding, ΔE = -6.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.176

Electronic energy of H2 binding, ΔE = -4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.239

Electronic energy of H2 binding, ΔE = -21.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.6kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -28.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.443

Electronic energy of H2 binding, ΔE = -26.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -12.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.7 kcal/mol

xyz coordinates: Download