Frustrated Lewis Pairs Database

FLPID: 0BP09013

FLP

LA-LB distance (d/Å):2.104

hydride affinity (ΔG°H/eV) :-4.95

proton affinity (ΔG°H+/eV) :7.74

HOMO-LUMO Gap (ΔEg/eV):7.6

hardness of LA (η/eV):0.139

softness of LA (S/eV):3.601

CM5 charge of LA (e):-0.200

CM5 charge of LB (e):0.137

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.163

Electronic energy of H2 binding, ΔE = -13.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.133

Electronic energy of H2 binding, ΔE = -4.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.283

Electronic energy of H2 binding, ΔE = -26.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -35.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -32.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.413

Electronic energy of H2 binding, ΔE = -33.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -33.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -23.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.5 kcal/mol

xyz coordinates: Download