Frustrated Lewis Pairs Database

FLPID: 0BP09012

FLP

LA-LB distance (d/Å):2.171

hydride affinity (ΔG°H/eV) :-4.73

proton affinity (ΔG°H+/eV) :7.79

HOMO-LUMO Gap (ΔEg/eV):7.5

hardness of LA (η/eV):0.138

softness of LA (S/eV):3.635

CM5 charge of LA (e):-0.182

CM5 charge of LB (e):0.127

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.167

Electronic energy of H2 binding, ΔE = -7.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.121

Electronic energy of H2 binding, ΔE = -3.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.245

Electronic energy of H2 binding, ΔE = -28.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -5.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.608

Electronic energy of H2 binding, ΔE = -27.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -14.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.234

Electronic energy of H2 binding, ΔE = -22.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.7 kcal/mol

xyz coordinates: Download