Frustrated Lewis Pairs Database

FLPID: 0BP09011

FLP

LA-LB distance (d/Å):2.082

hydride affinity (ΔG°H/eV) :-4.13

proton affinity (ΔG°H+/eV) :8.19

HOMO-LUMO Gap (ΔEg/eV):7.6

hardness of LA (η/eV):0.140

softness of LA (S/eV):3.573

CM5 charge of LA (e):-0.221

CM5 charge of LB (e):0.149

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.363

Electronic energy of H2 binding, ΔE = 4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 7.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.430

Electronic energy of H2 binding, ΔE = 6.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 7.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 16.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.772

Electronic energy of H2 binding, ΔE = -7.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -23.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.953

Electronic energy of H2 binding, ΔE = -3.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.718

Electronic energy of H2 binding, ΔE = -3.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.3 kcal/mol

xyz coordinates: Download