Frustrated Lewis Pairs Database

FLPID: 0BN16012

FLP

LA-LB distance (d/Å):1.728

hydride affinity (ΔG°H/eV) :-4.67

proton affinity (ΔG°H+/eV) :8.56

HOMO-LUMO Gap (ΔEg/eV):6.1

hardness of LA (η/eV):0.112

softness of LA (S/eV):4.450

CM5 charge of LA (e):-0.164

CM5 charge of LB (e):-0.207

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):2.996

Electronic energy of H2 binding, ΔE = 8.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 13.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.335

Electronic energy of H2 binding, ΔE = 18.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 18.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 26.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.282

Electronic energy of H2 binding, ΔE = -14.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -2.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -24.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -14.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.2 kcal/mol

xyz coordinates: Download