Frustrated Lewis Pairs Database

FLPID: 0BN16011

FLP

LA-LB distance (d/Å):1.713

hydride affinity (ΔG°H/eV) :-4.59

proton affinity (ΔG°H+/eV) :8.57

HOMO-LUMO Gap (ΔEg/eV):8.1

hardness of LA (η/eV):0.148

softness of LA (S/eV):3.377

CM5 charge of LA (e):-0.166

CM5 charge of LB (e):-0.211

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.167

Electronic energy of H2 binding, ΔE = 3.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 9.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.662

Electronic energy of H2 binding, ΔE = 12.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 12.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.329

Electronic energy of H2 binding, ΔE = -16.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -17.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):1.710

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.471

Electronic energy of H2 binding, ΔE = -15.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download